01 Physical chemistry
Mixtures, purity and separation
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What you should be able to do
- Choose separation methods from physical properties
- Distinguish elements, compounds and mixtures
Understand it
An element contains one type of atom; a compound has elements chemically combined in fixed proportions; a mixture has substances together without a fixed chemical ratio. Physical changes alter form or state, while chemical changes produce different substances.
Separation uses differences in properties. Filtration separates an insoluble solid from a liquid; evaporation recovers a non-volatile solute; distillation collects a volatile liquid. Fractional distillation improves separation of liquids with different but relatively close boiling points.
Chromatography separates substances by different affinities for mobile and stationary phases. Crystallisation exploits changing solubility, sublimation exploits direct solid-to-gas change, and a magnet can remove a magnetic component. Pure substances typically have characteristic sharp melting points at a stated pressure.
Work through an example
How would you recover both salt and water from salt solution?
Explanation: Use simple distillation: water vaporises and is condensed, while the non-volatile salt remains in the vessel.
Watch out: Filtration cannot remove a dissolved salt from its solution.
2 practice questions with answers
Try each question before opening its answer. These are original CampusNinja practice questions.
Question 1
Which method directly collects insoluble sand as a residue while water passes through the apparatus without boiling the mixture?
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Answer B: Filtration
Sand does not dissolve in water. Its particles remain on the filter paper as the residue while water passes through as the filtrate. Fractional distillation separates suitable liquid mixtures; sublimation requires a component that passes directly from solid to gas. Neither is needed for this mixture.
Question 2
A mixture of coloured soluble dyes is commonly separated by
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Answer D: Chromatography
In chromatography, dissolved dyes interact differently with the moving solvent and the stationary material, so they travel different distances. Decanting pours off a liquid but does not separate dissolved dyes. A magnet and hand picking do not distinguish these dissolved components.